or %USERPROFILE%AppData\Local\Cisco\Cisco AnyConnect Secure Mobility Client if not installed on a C: drive.
Navigate to Configuration > Remote Access VPN > Network Client Access > AnyConnect Client Profile.
Choose Add.
Give the profile a name.
Choose the Umbrella Security Roaming Client type from the Profile Usage dropdown list.
I know where the VPN settings are located IF you create the VPN through Network & Internet > VPN > Add a VPN Connection. Those settings are located at %AppData%\Microsoft\Network\Connections\Pbk folder.
Though the quickest way to create a pcf file is just do a remote session to your first mobile users computer. Enter the information in the vpn client, and then email yourself the pcf file it created.